Intramolecular π-π stacking and bromine interactions in (2,2′-bipyridine-κ2N,N′)-dibromo-cis-bis[1, 1-diphenylhydrazido(2-)]-molybdenum(VI)

Carlos Bustos; Christian Sánchez; Eduardo Schott; Maria Teresa Garland; Luis Alvarez-Thon

doi:10.1107/S1600536806043996

Intramolecular π-π stacking and bromine interactions in (2,2′-bipyridine-κ2N,N′)-dibromo-cis-bis[1, 1-diphenylhydrazido(2-)]-molybdenum(VI)

Carlos Bustos
, Christian Sánchez
, Eduardo Schott
, Maria Teresa Garland
, Luis Alvarez-Thon

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Molecules of the title compound, [Mo(C₁₂H₁₀N ₂)₂Br₂-(C₁₀H₈N ₂)], are linked via several weak C-H⋯Br interactions. The crystal structure shows similar unit cell parameters and packing scheme to two analogous previously reported structures. All three structures exhibit an intramolecular aromatic π-π interaction.

Original language	English
Pages (from-to)	m3104-m3106
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	11
DOIs	https://doi.org/10.1107/S1600536806043996
State	Published - Nov 2006
Externally published	Yes

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title = "Intramolecular π-π stacking and bromine interactions in (2,2′-bipyridine-κ2N,N′)-dibromo-cis-bis[1, 1-diphenylhydrazido(2-)]-molybdenum(VI)",

abstract = "Molecules of the title compound, [Mo(C12H10N 2)2Br2-(C10H8N 2)], are linked via several weak C-H⋯Br interactions. The crystal structure shows similar unit cell parameters and packing scheme to two analogous previously reported structures. All three structures exhibit an intramolecular aromatic π-π interaction.",

author = "Carlos Bustos and Christian S{\'a}nchez and Eduardo Schott and Garland, \{Maria Teresa\} and Luis Alvarez-Thon",

year = "2006",

month = nov,

doi = "10.1107/S1600536806043996",

language = "English",

volume = "62",

pages = "m3104--m3106",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "11",

}

Intramolecular π-π stacking and bromine interactions in (2,2′-bipyridine-κ2N,N′)-dibromo-cis-bis[1, 1-diphenylhydrazido(2-)]-molybdenum(VI). / Bustos, Carlos; Sánchez, Christian; Schott, Eduardo et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 62, No. 11, 11.2006, p. m3104-m3106.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Intramolecular π-π stacking and bromine interactions in (2,2′-bipyridine-κ2N,N′)-dibromo-cis-bis[1, 1-diphenylhydrazido(2-)]-molybdenum(VI)

AU - Bustos, Carlos

AU - Sánchez, Christian

AU - Schott, Eduardo

AU - Garland, Maria Teresa

AU - Alvarez-Thon, Luis

PY - 2006/11

Y1 - 2006/11

N2 - Molecules of the title compound, [Mo(C12H10N 2)2Br2-(C10H8N 2)], are linked via several weak C-H⋯Br interactions. The crystal structure shows similar unit cell parameters and packing scheme to two analogous previously reported structures. All three structures exhibit an intramolecular aromatic π-π interaction.

AB - Molecules of the title compound, [Mo(C12H10N 2)2Br2-(C10H8N 2)], are linked via several weak C-H⋯Br interactions. The crystal structure shows similar unit cell parameters and packing scheme to two analogous previously reported structures. All three structures exhibit an intramolecular aromatic π-π interaction.

UR - https://www.scopus.com/pages/publications/33750892084

U2 - 10.1107/S1600536806043996

DO - 10.1107/S1600536806043996

M3 - Article

AN - SCOPUS:33750892084

SN - 1600-5368

VL - 62

SP - m3104-m3106

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

Intramolecular π-π stacking and bromine interactions in (2,2′-bipyridine-κ2N,N′)-dibromo-cis-bis[1, 1-diphenylhydrazido(2-)]-molybdenum(VI)

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