A new hybrid organic-inorganic chain: [(Phen)Cu-μ-(κ2 O:O′-VP2O10H3)2-Cu(phen)] n

Diego Venegas-Yazigi; Andres Vega; Karen Valdes De La Barra; Marianela Saldias; Eric Le Fur

doi:10.1107/S0108270112026005

A new hybrid organic-inorganic chain: [(Phen)Cu-μ-(κ² O:O′-VP₂O₁₀H₃)₂-Cu(phen)] _n

Diego Venegas-Yazigi
, Andres Vega
, Karen Valdes De La Barra
, Marianela Saldias
, Eric Le Fur

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The structure of the title compound, poly[(dihydrogen-phosphato-κO) (μ₃-hydrogenphosphato)di-μ-xido-(1,10-phenanthroline)copper(II) vanadium(V)], [CuV(HPO₄)(H₂PO₄)O ₂(C₁₂H₈N₂)]_n , is defined by [(phen)Cu-μ-(κ² O:O′-VP₂O ₁₀H₃)₂-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they inter-digitate through the phen groups via π-π inter-actions.

Original language	English
Pages (from-to)	m200-m202
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	68
Issue number	7
DOIs	https://doi.org/10.1107/S0108270112026005
State	Published - Jul 2012
Externally published	Yes

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title = "A new hybrid organic-inorganic chain: [(Phen)Cu-μ-(κ2 O:O′-VP2O10H3)2-Cu(phen)] n",

abstract = "The structure of the title compound, poly[(dihydrogen-phosphato-κO) (μ3-hydrogenphosphato)di-μ-xido-(1,10-phenanthroline)copper(II) vanadium(V)], [CuV(HPO4)(H2PO4)O 2(C12H8N2)]n , is defined by [(phen)Cu-μ-(κ2 O:O′-VP2O 10H3)2-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they inter-digitate through the phen groups via π-π inter-actions.",

author = "Diego Venegas-Yazigi and Andres Vega and \{Valdes De La Barra\}, Karen and Marianela Saldias and \{Le Fur\}, Eric",

year = "2012",

month = jul,

doi = "10.1107/S0108270112026005",

language = "English",

volume = "68",

pages = "m200--m202",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

number = "7",

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TY - JOUR

T1 - A new hybrid organic-inorganic chain

T2 - [(Phen)Cu-μ-(κ2 O:O′-VP2O10H3)2-Cu(phen)] n

AU - Venegas-Yazigi, Diego

AU - Vega, Andres

AU - Valdes De La Barra, Karen

AU - Saldias, Marianela

AU - Le Fur, Eric

PY - 2012/7

Y1 - 2012/7

N2 - The structure of the title compound, poly[(dihydrogen-phosphato-κO) (μ3-hydrogenphosphato)di-μ-xido-(1,10-phenanthroline)copper(II) vanadium(V)], [CuV(HPO4)(H2PO4)O 2(C12H8N2)]n , is defined by [(phen)Cu-μ-(κ2 O:O′-VP2O 10H3)2-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they inter-digitate through the phen groups via π-π inter-actions.

AB - The structure of the title compound, poly[(dihydrogen-phosphato-κO) (μ3-hydrogenphosphato)di-μ-xido-(1,10-phenanthroline)copper(II) vanadium(V)], [CuV(HPO4)(H2PO4)O 2(C12H8N2)]n , is defined by [(phen)Cu-μ-(κ2 O:O′-VP2O 10H3)2-Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they inter-digitate through the phen groups via π-π inter-actions.

UR - https://www.scopus.com/pages/publications/84863512225

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DO - 10.1107/S0108270112026005

M3 - Article

AN - SCOPUS:84863512225

SN - 0108-2701

VL - 68

SP - m200-m202

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 7

ER -

A new hybrid organic-inorganic chain: [(Phen)Cu-μ-(κ² O:O′-VP₂O₁₀H₃)₂-Cu(phen)] _n

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