3,5-Dimethyl-4-[(E)-(2-nitrophenyl)diazenyl]-1-(2,3,4,5, 6-pentafluorophenyl)-1H-pyrazole

Luis Alvarez Thon; Carlos Bustos; Fernando Diaz-Marín; Maria Teresa Garland; Ricardo Baggio

doi:10.1107/S0108270112048573

3,5-Dimethyl-4-[(E)-(2-nitrophenyl)diazenyl]-1-(2,3,4,5, 6-pentafluorophenyl)-1H-pyrazole

Luis Alvarez Thon
, Carlos Bustos
, Fernando Diaz-Marín
, Maria Teresa Garland
, Ricardo Baggio

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, C₁₇H10F5N₅O₂, is described and compared with its 4-nitrophenyl isomer [Bustos, Sánchez, Schott, Alvarez-Thon & Fuentealba (2007). Acta Cryst. E63, o1138-o1139]. The title molecule presents its nitro group split into two rotationally disordered components, which in conjunction with the rotation of the 'unclamped' rings constitute the main molecular differences. Packing is directed by a head-to-tail type 'I' C - F⋯F - C interaction, generating double-chain strips running along [100]. These substructures are interlinked by a variety of weak F⋯F, O⋯F, F⋯π and O⋯π interactions.

Original language	English
Pages (from-to)	101-104
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	69
Issue number	1
DOIs	https://doi.org/10.1107/S0108270112048573
State	Published - Jan 2013
Externally published	Yes

Access to Document

10.1107/S0108270112048573

Cite this

@article{ccb8937a42d74f35934e06edec944a5d,

title = "3,5-Dimethyl-4-[(E)-(2-nitrophenyl)diazenyl]-1-(2,3,4,5, 6-pentafluorophenyl)-1H-pyrazole",

abstract = "The title compound, C17H10F5N5O2, is described and compared with its 4-nitrophenyl isomer [Bustos, S{\'a}nchez, Schott, Alvarez-Thon \& Fuentealba (2007). Acta Cryst. E63, o1138-o1139]. The title molecule presents its nitro group split into two rotationally disordered components, which in conjunction with the rotation of the 'unclamped' rings constitute the main molecular differences. Packing is directed by a head-to-tail type 'I' C - F⋯F - C interaction, generating double-chain strips running along [100]. These substructures are interlinked by a variety of weak F⋯F, O⋯F, F⋯π and O⋯π interactions.",

author = "\{Alvarez Thon\}, Luis and Carlos Bustos and Fernando Diaz-Mar{\'i}n and Garland, \{Maria Teresa\} and Ricardo Baggio",

year = "2013",

month = jan,

doi = "10.1107/S0108270112048573",

language = "English",

volume = "69",

pages = "101--104",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

number = "1",

}

TY - JOUR

T1 - 3,5-Dimethyl-4-[(E)-(2-nitrophenyl)diazenyl]-1-(2,3,4,5, 6-pentafluorophenyl)-1H-pyrazole

AU - Alvarez Thon, Luis

AU - Bustos, Carlos

AU - Diaz-Marín, Fernando

AU - Garland, Maria Teresa

AU - Baggio, Ricardo

PY - 2013/1

Y1 - 2013/1

N2 - The title compound, C17H10F5N5O2, is described and compared with its 4-nitrophenyl isomer [Bustos, Sánchez, Schott, Alvarez-Thon & Fuentealba (2007). Acta Cryst. E63, o1138-o1139]. The title molecule presents its nitro group split into two rotationally disordered components, which in conjunction with the rotation of the 'unclamped' rings constitute the main molecular differences. Packing is directed by a head-to-tail type 'I' C - F⋯F - C interaction, generating double-chain strips running along [100]. These substructures are interlinked by a variety of weak F⋯F, O⋯F, F⋯π and O⋯π interactions.

AB - The title compound, C17H10F5N5O2, is described and compared with its 4-nitrophenyl isomer [Bustos, Sánchez, Schott, Alvarez-Thon & Fuentealba (2007). Acta Cryst. E63, o1138-o1139]. The title molecule presents its nitro group split into two rotationally disordered components, which in conjunction with the rotation of the 'unclamped' rings constitute the main molecular differences. Packing is directed by a head-to-tail type 'I' C - F⋯F - C interaction, generating double-chain strips running along [100]. These substructures are interlinked by a variety of weak F⋯F, O⋯F, F⋯π and O⋯π interactions.

UR - https://www.scopus.com/pages/publications/84872045648

U2 - 10.1107/S0108270112048573

DO - 10.1107/S0108270112048573

M3 - Article

C2 - 23282925

AN - SCOPUS:84872045648

SN - 0108-2701

VL - 69

SP - 101

EP - 104

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 1

ER -

3,5-Dimethyl-4-[(E)-(2-nitrophenyl)diazenyl]-1-(2,3,4,5, 6-pentafluorophenyl)-1H-pyrazole

Abstract

Access to Document

Other files and links

Fingerprint

Cite this